Figure 7: Decay scheme of a radioactive sodium (24Na) nucleus. With a half- life of 15 hours, it decays by beta decay to an excited magnesium (24Mg). 26Al is a radioactive isotope that decays into 26Mg, a stable isotope, with a The reason is that because of its radioactive decay, the 26Al/27Al ratio . three stable magnesium isotopes (24Mg, 25Mg, and 26Mg) and 27Al (the. Since radioactive decay represents the transformation of an unstable .. (3-‐23). Taking the derivative of Equation (3-‐21) and simplifying,. (3-‐24) .. Example: Consider a sample of organic material that contains 1 mg of C. Suppose it has a.

### Sodium | chemical isotope | falgir.info

That's the half-life of potassium We know, after that long, that half of the sample will be left. Whatever we started with, we're going to have half left after 1. Divide both sides by N0. And then to solve for k, we can take the natural log of both sides.

The natural log is just saying-- to what power do I have to raise e to get e to the negative k times 1. So the natural log of this-- the power they'd have to raise e to to get to e to the negative k times 1. Or I could write it as negative 1.

That's the same thing as 1. We have our negative sign, and we have our k. And then, to solve for k, we can divide both sides by negative 1. And so we get k. And I'll just flip the sides here. And what we can do is we can multiply the negative times the top. Or you could view it as multiplying the numerator and the denominator by a negative so that a negative shows up at the top. And so we could make this as over 1. Let me write it over here in a different color. The negative natural log-- well, I could just write it this way.

If I have a natural log of b-- we know from our logarithm properties, this is the same thing as the natural log of b to the a power. And so this is the same thing. Anything to the negative power is just its multiplicative inverse. So this is just the natural log of 2. So negative natural log of 1 half is just the natural log of 2 over here.

So we were able to figure out our k. It's essentially the natural log of 2 over the half-life of the substance.

## Radiometric dating

So we could actually generalize this if we were talking about some other radioactive substance. And now let's think about a situation-- now that we've figured out a k-- let's think about a situation where we find in some sample-- so let's say the potassium that we find is 1 milligram.

I'm just going to make up these numbers. And usually, these aren't measured directly, and you really care about the relative amounts. But let's say you were able to figure out the potassium is 1 milligram. And let's say that the argon-- actually, I'm going to say the potassium found, and let's say the argon found-- let's say it is 0.

So how can we use this information-- in what we just figured out here, which is derived from the half-life-- to figure out how old this sample right over here? How do we figure out how old this sample is right over there? Well, what we need to figure out-- we know that n, the amount we were left with, is this thing right over here.

### Radiometric dating - Wikipedia

So we know that we're left with 1 milligram. And that's going to be equal to some initial amount-- when we use both of this information to figure that initial amount out-- times e to the negative kt. And we know what k is. And we'll figure it out later. So k is this thing right over here.

So we need to figure out what our initial amount is. We know what k is, and then we can solve for t. How old is this sample?

We saw that in the last video. So if you want to think about the total number of potassiums that have decayed since this was kind of stuck in the lava. And we learned that anything that was there before, any argon that was there before would have been able to get out of the liquid lava before it froze or before it hardened.

So maybe I could say k initial-- the potassium initial-- is going to be equal to the amount of potassium 40 we have today-- 1 milligram-- plus the amount of potassium we needed to get this amount of argon We have this amount of argon 0. The rest of it turned into calcium And this isn't the exact number, but it'll get the general idea.

And so our initial-- which is really this thing right over here. I could call this N0. This is going to be equal to-- and I won't do any of the math-- so we have 1 milligram we have left is equal to 1 milligram-- which is what we found-- plus 0. And then, all of that times e to the negative kt. And what you see here is, when we want to solve for t-- assuming we know k, and we do know k now-- that really, the absolute amount doesn't matter.

What actually matters is the ratio. The temperature at which this happens is known as the closure temperature or blocking temperature and is specific to a particular material and isotopic system. These temperatures are experimentally determined in the lab by artificially resetting sample minerals using a high-temperature furnace.

As the mineral cools, the crystal structure begins to form and diffusion of isotopes is less easy. At a certain temperature, the crystal structure has formed sufficiently to prevent diffusion of isotopes.

This temperature is what is known as closure temperature and represents the temperature below which the mineral is a closed system to isotopes. Thus an igneous or metamorphic rock or melt, which is slowly cooling, does not begin to exhibit measurable radioactive decay until it cools below the closure temperature.

The age that can be calculated by radiometric dating is thus the time at which the rock or mineral cooled to closure temperature.

This field is known as thermochronology or thermochronometry. The age is calculated from the slope of the isochron line and the original composition from the intercept of the isochron with the y-axis. The equation is most conveniently expressed in terms of the measured quantity N t rather than the constant initial value No. The above equation makes use of information on the composition of parent and daughter isotopes at the time the material being tested cooled below its closure temperature.

This is well-established for most isotopic systems. Plotting an isochron is used to solve the age equation graphically and calculate the age of the sample and the original composition.

Modern dating methods[ edit ] Radiometric dating has been carried out since when it was invented by Ernest Rutherford as a method by which one might determine the age of the Earth. In the century since then the techniques have been greatly improved and expanded. The mass spectrometer was invented in the s and began to be used in radiometric dating in the s.

It operates by generating a beam of ionized atoms from the sample under test. The ions then travel through a magnetic field, which diverts them into different sampling sensors, known as " Faraday cups ", depending on their mass and level of ionization. On impact in the cups, the ions set up a very weak current that can be measured to determine the rate of impacts and the relative concentrations of different atoms in the beams. Uranium—lead dating method[ edit ] Main article: Uranium—lead dating A concordia diagram as used in uranium—lead datingwith data from the Pfunze BeltZimbabwe.

This scheme has been refined to the point that the error margin in dates of rocks can be as low as less than two million years in two-and-a-half billion years. Zircon has a very high closure temperature, is resistant to mechanical weathering and is very chemically inert.

Zircon also forms multiple crystal layers during metamorphic events, which each may record an isotopic age of the event. This can be seen in the concordia diagram, where the samples plot along an errorchron straight line which intersects the concordia curve at the age of the sample. Samarium—neodymium dating method[ edit ] Main article: Samarium—neodymium dating This involves the alpha decay of Sm to Nd with a half-life of 1.

Accuracy levels of within twenty million years in ages of two-and-a-half billion years are achievable. Potassium—argon dating This involves electron capture or positron decay of potassium to argon Potassium has a half-life of 1. Rubidium—strontium dating method[ edit ] Main article: Rubidium—strontium dating This is based on the beta decay of rubidium to strontiumwith a half-life of 50 billion years. This scheme is used to date old igneous and metamorphic rocksand has also been used to date lunar samples.

Closure temperatures are so high that they are not a concern. Rubidium-strontium dating is not as precise as the uranium-lead method, with errors of 30 to 50 million years for a 3-billion-year-old sample.

Uranium—thorium dating method[ edit ] Main article: Uranium—thorium dating A relatively short-range dating technique is based on the decay of uranium into thorium, a substance with a half-life of about 80, years. It is accompanied by a sister process, in which uranium decays into protactinium, which has a half-life of 32, years.

While uranium is water-soluble, thorium and protactinium are not, and so they are selectively precipitated into ocean-floor sedimentsfrom which their ratios are measured. The scheme has a range of several hundred thousand years. A related method is ionium—thorium datingwhich measures the ratio of ionium thorium to thorium in ocean sediment. Radiocarbon dating method[ edit ] Main article: Carbon is a radioactive isotope of carbon, with a half-life of 5, years, [25] [26] which is very short compared with the above isotopes and decays into nitrogen.

Carbon, though, is continuously created through collisions of neutrons generated by cosmic rays with nitrogen in the upper atmosphere and thus remains at a near-constant level on Earth. The carbon ends up as a trace component in atmospheric carbon dioxide CO2. A carbon-based life form acquires carbon during its lifetime. Plants acquire it through photosynthesisand animals acquire it from consumption of plants and other animals. When an organism dies, it ceases to take in new carbon, and the existing isotope decays with a characteristic half-life years.

The proportion of carbon left when the remains of the organism are examined provides an indication of the time elapsed since its death. This makes carbon an ideal dating method to date the age of bones or the remains of an organism. The carbon dating limit lies around 58, to 62, years. However, local eruptions of volcanoes or other events that give off large amounts of carbon dioxide can reduce local concentrations of carbon and give inaccurate dates.

The releases of carbon dioxide into the biosphere as a consequence of industrialization have also depressed the proportion of carbon by a few percent; conversely, the amount of carbon was increased by above-ground nuclear bomb tests that were conducted into the early s. Also, an increase in the solar wind or the Earth's magnetic field above the current value would depress the amount of carbon created in the atmosphere.